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It will work, but your stereoacuity will not exist. You will be immersed and be able to turn your head to look at things and interact with things in VR just fine. You just won't have binocular vision, just like your real life.
Edit: What specifically is wrong with your left eye?
There really isn't much difference in they retina's ability to develop between a 30yo and a 44yo. I'm guessing you have amblyopia because of a strabismus and your doctor meant that you could have surgery to repair the strabismus but it may not improve your vision much if any. This type of problem is much easier to fix in a person 7yo or younger, but it is still possible to get some improvement in older people.My retina did not fully develop. I am 44 now. An eye doctor about 4 years ago told me that if I were only 30, there is a surgery that would have had a very good chance of fixing it. But at 40, I was too old and I would have higher risks where the surgery might make it worse. I chose to leave it as it is now.