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If it was hanging at the POST screen, that's a clear indication it isn't related to the OS, because you haven't gotten to the OS yet. Besides, to answer your question, XP x86 would still run, you just won't be able to use all your memory. XP x64 would run and use it all, however.Am I right in thinking Win XP can't run with 4 GB RAM?
if you run Windows 2k3 server 32bit you can have a lot more than 4GB ...