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Simplest thing you can do? Change the "Power Control" slider in AMD Overdrive from 0 to -20.
This reduces the maximum amount of power the card is allowed to draw, which will lead to lower load power consumption and temperature at the cost of performance.
Yes, that is hot enough to be concerned with. Sounds like your card is bad or your case has no airflow, or you live in Hades .Hmm, so I lowered the "power control" slider down to -20%, however my load temps are exactly the same at 103 degrees. I guess that feature isn't working yet or something? Is 103 Celsius hot enough to be concerned about at all? I don't think i've ever had a videocard run this hot before.
What card do you have? When is it running at 100 degrees? Are your fans at 100% at this stage? You're not really giving us enough info to work with here.
Use MSI Afterburner to undervolt it.