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The T Junction Max Temperature is the temperature at which Core CPUs are designed to throttle down in order to prevent damage. There is a lot of discussion about it as Intel doesn't disclose exactly what this temperature is for its desktops CPUs.
I know what Tjunction is, but why does it matter if we're trying to avoid getting temps that high anway?
I think the point you're missing is: no one outside of Intel knows the actual real Tjunction temp on any given Q6600, and Intel ain't telling. So we're all just using 95C or 100C as a basis for comparison - but again, no one outside of Intel knows EXACTLY what the Tjunction temp of any given specific Q6600 is.
That's part of what makes this whole temp reading process so iffy in the first place, we don't know the exact temps, ever. I have a Q6600 G0 stepping and RealTemp comes with 95C as Tjunction - I see no reason to use anything else so that's where I'll let it as default.