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Are you expecting up to read you're mind?
man, that would be fantastic, but even better would be if you could read my computer's mind and convince it to run L4D really well.
Kneejerk reactions:
First: Pentium....ew...
Second: Windows 2k3? Why? I assume you mean Server 2k3...Not a gaming operating system...Yes, I know it works. And Yes, I also know it is not optimal.
Question: What resolution are you running, or trying to run?
What is running in the backround when you are playing?
What settings are you using, exactly?
What happens if you turn off AA (assuming it's on)?
Do you have that multicore rendering thing disabled in options -> video (i think that is the correct path)?
Runs very smoothly on my mediocre rig.
Audio drivers, perhaps, how about them?