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So with OEM Vistas, you can't go from 32 to 64bit with the same key correct? That is only for retail?
Vista keys are 32 bit / 64 bit interchangeable, meaning if you have a legit Vista key, it can be used to install the given 32 bit edition it is designed for or the 64 bit edition as well.
XP keys are a bit more tricky in that XP Home keys don't work for XP Pro, XP OEM keys don't work for retail and vice versa, XP MSDN keys don't work for OEM, that sort of thing.
That's because the discs are the same, aside from the x86 or x64 platform. The key you enter determines the license type and version installed.so, the key does work on both versions, even if it's not the exact right install disc and even if the key is OEM