Only in OpenGl games not DxOf course you can force triple buffering through the driver. Nvidia has been doing it in DirectX apps automatically since I can remember. At least 6 years. You can even force it in OpenGL, but there you have to do it manually afaik. Don't know how it's handled on the Radeon side.
As I said, I use Dxtory, and if I disable vsync, I get tearing. Could be that it helps a little bit, but not much.