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I think it depends on what you plan to do with them. If they are screenshots for print, that will be delivered by hard-copy, I'd go with PNG. If you plan to post them on a website or a forum, I'd go with JPG.
I understand that. What I meant was, how or through what medium, these images will be displayed. If it's on the web, you wouldn't want PNG files, due to the higher file size. If this is for a printed guide, such as one I hand out to my new-hires, PNG is fine, and in fact is preferred.Well, most screenshots are designed to illustrate something, for example "how do I deactivate UAC"
I understand that. What I meant was, how or through what medium, these images will be displayed. If it's on the web, you wouldn't want PNG files, due to the higher file size. If this is for a printed guide, such as one I hand out to my new-hires, PNG is fine, and in fact is preferred.
I'd rather downgrade quality than be stuck with something that may not scale well.
You must be using better software than I am. My PNG files are always quite a bit larger than JPGs. PNGs are definitely a higher quality picture, which would support enlargement much better. If you are scaling down the images, you won't see as much of a difference between the two.