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It should, and it will clock is self down. Will it affect performance? Yes. How much will vary based on your machine.It will work.
Putting memory in a system that is faster than the FSB does not increase performance because it can only be read/write at the rate the path can feed it. If his bus was 400MHZ, then 667 DDR would cause performance loss, but even then, you wouldn't notice outside of synthetic benchmarks. And those are fake.hes going to be running 800 ram at 667 ram speed. There will be a performance difference. He just may not notice it.