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That somewhat depends on the processor...
If it's a single core non hyper treaded like a older amd and your going dual core....
Then you might need to reinstall to get multiprocessor aware O/S but more than likely just plug and go.
CPU: Intel E8400 C2D @ 3.6Ghz
Case: Lian Li PC-A70b w/ W-75 Side Panel
FROM a E8400 (in my sig) to a Q9650
No way, just changed an E8400 for an E8600 and no need to reinstall os
His point was that it's not clear if you upgraded to that CPU, or are planning on upgrading from that CPU. Which is meaningless; if you'd already upgraded, then this thread would have taken a different form.
Since you already have a multicore CPU, Windows already has the multiprocessor HAL installed and you won't have to reload another HAL or the entire OS to enable that support.
EDIT: took too long to hit submit...
The following CPUs all normally use the 32-bit ACPI multiprocessor HAL:
All Northwood-C Pentium 4 CPUs (without exception)
The Pentium 4 Northwood-B 3.06 GHz
All Prescott Pentium 4 CPUs in S478 (without exception)
(These Netburst architecture CPUs all support HyperThreading Technology.)
The Core Duo (not Core 2 Duo) in LGA775 supports the 32-bit ACPI multiprocessor HAL, but not a 64-bit HAL.
Surprisingly, current-model single-core *Celerons* actually support the 32-bit and 64-bit ACPI HALs (either single-core or multicore), despite having only one active core.
Celeron DC and Pentium DC CPUs support the 32-bit and 64-bit MP HALs directly, but not in VMs, as they do not support VT.
Core2Duo and Core2Quad CPUs (with limited exceptions) support both 32-bit and 64-bit MP HALs and support VT modes (however, some C2Ds and even some C2Qs don't support VT modes), so there may be some VM reconfiguration needed if upgrading from a CPU that doesn't support VT to one that does.