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I have 24 gigs of RAM on windows 7 64 and I want to be able to load full games onto a ram drive, which is definitely going to be better than the system file caching for loading levels, maps, etc
I also have 24GB and use this
I use it for temp files and scratch disk for CS5. For loading entire apps in ramdism I didnt notice much if any real world performance over an SSD drive