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I dont trust any of Microsofts products for backups (heck, thats why we even need backups, cause we use Microsoft crap). I'd settle for Ghost, etc.
SyncToy would work perfectly for you. My wife has it set to do her e-mail, iTunes folder, pictures, and game saves. She runs the software, clicks one buttong and anything new/changed since the last run is sent off to our server.I am just backing up data; itunes (who wants to rip all that again) some writting, etc.