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Pretty sure ff stands for fully functional.
Test your psu with a multi if possible.
FF isn't listed in the manual as a valid POST code. Are you saying it starts at FF and doesn't progress from there?
I don't think it's a PSU issue, I think you're motherboard or CPU(s) are on the way out. First you should try putting in a new CMOS battery (CR2032), funny things apparently happen when they die, and it's super cheap to get them. If that doesn't fix the problem, you could try a replacement PSU (will still be just as old as the current one, though, they used proprietary connectors), but I don't think that's it.
If you have 2 CPUs, try taking CPU1 out and just use a single memory stick (take out the video card, too, you don't need it to read the POST codes and it removes a variable, same goes for all the drives, etc., go right to basics!). If that doesn't work, try putting CPU1 into the socket for CPU0. If at some point it starts working, start adding memory and the second CPU back one at a time until it fails, and you've found your bad part. If not, you definitely need a new mobo. Look for bulging capacitors on the board.
What do you use this ancient power guzzler for?
They're hex codes, FF is just the highest possible display value, or conversely, the equivalent of "-1," which is why I'm curious if datum's board starts at FF and stays put (bad) or cycles through many and ends there (potentially not bad, depending on the beeps, if any). Different brands use different values for when a system has completed post and is ready for the OS. I have a Gigabyte board that will stop on A0 or d4 depending on if it was a cold or warm start.
Cn you describe the noise? metallic grinding=worn fan bearings (to be expected, really), high-pitched whine = coil sheathing & coils wearing out (not the end of the world, but annoying).
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There is no grinding. And not really all that high-pitched. It's just loud. And has been loud for years. I don't recall it having changed. It behaved the same way years ago when it booted.
I do recall one difference, upon the initial bootup, the noise was loud and as it booted, the fans slowed down. Here, they never slow down. Just run ad infinitum at the highest speed/noise/pitch level.
My question is, if the power supply fried, why do the fans turn on? Nothing should be turning on. The power button should result in no action.
One thought I have is to get another, possibly stripped Ultra 40 M2 for a token price and just insert my video card, RAM and HDDs into it. I cannot see how these machines are worth anything even when working. And a parts one should be scrap metal territory. I mean it's 2005-2006 territory.
I don't even know what the point is of resurrecting this machine. It's noisy, power-hungry, very heavy and something else will break on it. Maybe keep it as a spare, or a sandbox for Linux experiments.
A single motherboard is likely to cost more than an entire machine, which is strange.