ASUS is giving me an opportunity to RMA the board.
I'm doubtful that it's a case of limited CPU overclock as the volts I have the system at to achieve 4.0 are next to nothing over stock - WHEN the system boots I have zero issues, it just strikes early in the BIOS loading portion of the system - hence I'm thinking I may not have enough voltage going to some portion of the board.
In regards to the VGA - I don't think using another DVI connection on my VGA card is the answer - I have four to pick from and have never had a prior issue with the card on my previous system - I'm still at a loss for this one.
Well, if you do rma and it fixes your issue, let me know, cause i may rma mine. It may explain why i have to pump a stupid ammount of voltage through mine to get stability at 4.0