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Possibly slightly off topic, but that much memory almost necessitates ECC / Buffering. Single--bit errors occur as a function of memory size, that much memory means random little corruptions will occur more likely on a per-system basis than on a more "normal" system with 8 or 16GB of RAM.
On a more on-topic note, occasionally occupying all DIMM slots requires looser timings and possibly not even using the memory at it's highest rated speed. Aside from that, it should be plug-and-play. Checking the manufacturer's recommended/tested memory list helps with applications like this.