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I have a feeling windows key More seriously, why the hell would you want to disable a key? Other than scroll lock (which i only used last 8yrs ago) there is not a single other key I don't use.
http://johnhaller.com/jh/useful_stuff/disable_windows_key/
You don't use scroll lock? I use it hundreds of times a day... I guess you only have one computer? Or you're using a sw kvm.
I've disabled my caps lock key because it serves no purpose (Windows.) I'm currently looking for a way to disable it in *Nix.